线膨胀系数也是不同的,百 莉所以在在降温过栏甲栩科州 在在降温过程中材料内 部也会产生内应力,内应力的产生可以诱发大量的位 错,使材料的矫顽力、剩磁、磁滞损耗增加 引。于旭 光 指出合金在低温下,原子热振动振幅减小,使I司向 排列的磁矩密度提高,由于原子问相互作用的变化,还 可使部分偏离磁化强度方向的磁矩转向磁化强度方 向,取向度增大,从而使材料的矫顽力、剩磁、磁滞损耗 增加。随着温度的降低,材料晶粒减小,由内应力模 |l3 ]晶粒尺寸减小,晶界总面积增大,由晶界引起 ,的内应力增加,矫顽力增大。 丽一 合金回火后内应力、位错等缺陷大量减少,饱和磁 感应强度增加,但是饱和磁感应强度是结构不敏感量, 主要由材料成分决定,2J4合金成分确定,所以两者变 化不大。回火过程中,少量细小、弥散析第二相的析出 使合金获得高的矫顽力,同时剩磁增加。磁滞损耗受 饱和磁感应强度、剩余、矫顽力影响,磁滞损耗和矫顽 力为结构敏感量,矫顽力越大,磁滞损耗越大,所以回 火后磁滞损耗增加。 热胀冷缩是固体物质的共性,冷处理后,材料体积 收缩,使材料内的空位、微孔等得到弥合,提高了磁体 的致密度,从而提高了剩磁… 。同时品格产生收缩, 原子间距减少,材料内部内能升高,在热胀冷缩过程 中,磁体在不同方向的热膨胀系数不一样,每种元素的 总之,上述实验研究验证了前述显微组织和磁畴 观察及分析的正确性。 4 结 论 (1) 回火处理后虽然会使试样内应力,位错等缺 陷减少,但是析出相的大量出现导致合金饱和磁感应 强度、剩磁、矫顽力、磁滞损耗增加。 (2)冷处理后,材料体积收缩、致密度增加、内应 力增加等因素导致合金饱和磁感应强度、剩磁、矫顽 力、磁滞损耗增加,并随着温度的降低,上述磁性能有 增强的趋势。 参考文献: n 1 Liu Zhien.Fundamentals of materials science(Versio“3) r M].Xi’an:Northwestern Polytechnical Unviversity Press,2007. r2]Zhu Fangzhen,Bi Xiaofang,Zhang Shanqlng・Phase “ formation and magnetic properties of annealed Fe5。2 Co46 V1.8 alloy[J].Vacuum,2004,75:33—38・ r3]Duckham A,Zhang D Z,Liang D・et a1.Temperatu 。de- Dendent mechanica1 properties of ultra-fine grained FeCo一 2VEJ].Acta Materialia,2003,51:4083—4093・ r4]Sundar R S,Deevi S C.Effect of heat—treatment on the —r。。m temperature ductility。f an。rdered intermetallic Fe— Co-V alloy叭.Materials Science and Engineering,2o。4, A369:164—169・ . 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Study on limit contents of MgO expansion agent in hydraulic concrete CHEN Changli ,LI Weiwei ,LI I iangchuan ,CHEN Rongfei0 (1.School of Materials and Architecture Engineering,Guizhou Normal University,Guiyang 550025,China; 2.School of Civil Engineering,Guizhou University,Guiyang 550025,China) Abstract:In order to meet the requirement for the autogenic volume—expanding deformation of hydraulic concrete mixed with light—burned magnesium oxide(MgO)and promote the application of MgO concrete,the autoclave test was carried out with“simulation mortar”specimen which using equivalent amount sand to replace coarse aggregate in the concrete.The result shows that the autoclave—treated expansibility of the specimen made by this simulation method was smaller than that of cement paste,cement mortar and grade—one concrete and the MgO limit contents acquired by this method is higher than current methods.If the MgO limit contents are determined at the MgO contents correspond to the inflection point of the curve that the autoclave——treated expansibility var—— ying with MgO contents,then the MgO limit contents can reach l2 with simulation mortar specimen when the fly ash content was 40 in the concrete. Key words:hydraulic concrete;simulation mortar;MgO limit contents;autoclave—treated expansibility : c : : c c c每c c 每 匀c c c c 劫 c c c匀c c c c c每 每c每 c c c c (上接第99页) [io]Du Zhongze,He Tao,Fu Hanguang,et a1.Effect of Tempering treatment on magnetic properties of uItra fine—grained 2J4 hysteresis alloy ̄J].Matallic Functiona1 Materia1s,2007,14(6):卜4. [1 1] Wang Qifan.Study on modification of NdFeB by cryo alloy[-J].The Chinese Journal of Nonferrous Metals, 2000,10(6):891—894. [13] Zhong Wending.The ferromagnetism[M].Beijing:Sci— ence Press,1998. [14]Xiong Liang,LI Yimin,He Hao,et aL Effects of micro structure and impurity on magnetm properties of metal genic treatmentED].Taiyuan:Taiyuan University of Sci ence Techonogv,2010. injection molding Fe一50 Ni alloy[J].The Chinese Journal of Nonferrous Metals,2011,21(4):821 827. [12]Chen Ding,Li Wenxian.Cryogenic treatment of AI and A1 Study on temperature characteristics of hysteresis properties of Fe。Co alloy I I Chunhong ,I UAN Baifeng ,LI Feng。,MA Yilong ,HUANG Si , CHEN Lin .CAO Chong 。LI Ning (1.School of Metallurgy and Materials Engineering, Chongqing University of Science and Technology,Chongqing 401331,China; 2.School of Materials Science and Engineering,Chongqing University,Chongqing 400044,China: 3.Chongqing Materials Research Institute,Chongqing 400707,China; 4.Military Representative Office of PI A in 307 Factory,Nanjing 210006,China) Abstract:2J4 alloy is one of the hysteresis Fe—Co alloys with high hysteresis properties,has been widly used in aerospace as hysteresis motor,navigated gyroscope,DC motor,relay.The temperature characteristics of hystere— sis properties of 2J4 alloy has been investigated in this paper.The alloys were tempered and cold treated at dif— ferent temperatures.The results indicated that there were some precipitated phases after tempering,which can pin domain boundary movement,thus leading to coercivity and remanence higher,hysteresis loss larger.After cold treatment,volume shrinkaged,the material density and internal stress increased,thus leading to coercivi— ty,saturation magnetization and remanence higher,hysteresis loss larger.In order to apply reference for further improving the magnetic properties of hysteresis motor selection of magnetic hysteresis alloy. Key words:2J4 alloy;tempering;cold treatment;magnetic properties